1.3.4 Substances of concern

Risks may arise directly from CO2 (see 1.3.1 to 1.3.3) or from its associated incidental substances, saline formation water, hydrocarbons, mobilised substances from rock or soil and indirectly from the geomechanical reaction of the storage environment (see 1.3.5). For monitoring purposes, rRisk assessments need to specify possible locations of leakage, magnitudes and impacts of possible incidents. Though the discussion of risks initially often was restricted to CO2, all of the risks require adequate monitoring.

Incidental associated substances

Depending on the capture technology, the CO2 phase may contain various incidental associated substances, such as SO2, NOx, CO, H2S, He, N2, O2, Ar, Hg, As, Se, and other trace elements. These impurities pose potential risks or may affect the level of risks due to their various potential impacts on the storage complex and on health, environmental and safety issues: Some species can be toxic, others form acids (SOx, NOx, H2S) that could cause corrosion problems, alteration of reservoir and caprocks, or the mobilisation of heavy metals from soils or aquifer rocks, which is of particular concern in freshwater aquifers.

Whether these minor components will cause risks in addition to effects caused by the CO2 itself, depends on the concentration of these impurities and the subjects exposed to them. These risks need to be assessed individually for each separated CO2 stream and storage project. For many risks, the monitoring of one indicator or proxy may be sufficient as long as the impurities are in the CO2-bearing phase. Detection of CO2 may be sufficient for early warning purposes.

Formation fluids

In an incident of leakage, formation fluids, phases naturally present in the storage formation or the overburden may migrate together with the CO2-rich phase to the surface and affect protected goods. Mobilised formation brines, natural gas or crude oil may be eco-toxic or pose risks to human health and safety. The displacement of formation water from saline aquifers is seen as a particular risk for freshwater aquifers. As water is almost incompressible, the injection of pressurised CO2 will push formation brine away from the injection wells. Displaced brine can potentially migrate or leak through fractures or wells into shallow aquifers and may thereby contaminate resources used for drinking water extraction.

Rock and/or soil constituents

Rock and/or soil constituents can be mobilised by various geochemical reactions. At depth, supercritical CO2 is an excellent solvent for organic material that may be extracted from reservoir or caprocks. The solubility of organics will decrease during fluid ascent according to the pressure and temperature conditions along the flow path. Precipitation of higher hydrocarbons may lead to permeability reductions in porous media. In open fractures such phases may be transported as mixtures with fluids of lower viscosity. Subsurface water and CO2 can react with wall rocks, e.g. mobilising toxic heavy metals or just ubiquitous formation water constituents.

If impurities or mobilised substances pose additional risks to CO2 leakage, than these risks have to be addressed by monitoring as well. For example at injection facilities for H2S-bearing CO2 both gaseous species should be monitored because of occupational safety, to avoid asphyxiation by CO2 or poisoning by H2S. Well materials may need more intensive monitoring when the concentrations of corrosion-enhancing substances (acidic gases, H2O, O2, Hg) exceed material-specific critical levels.